The study by the World Economic Forum (WEF) pinpointed firms in countries as diverse as Costa Rica, Egypt and China.
The WEF said it showed that global "green" businesses were not the only ones with sustainability credentials.
The report looked at 1,000 companies in the developing world.
Co-authored by management consultants Boston Consulting Group (BCG), the study said the findings were doubly interesting "given the challenges faced by emerging market companies which often have to deal with multiple problems".
It said these local difficulties ranged from substandard infrastructure and weak environmental regulatory regimes, to acute talent shortages and underdeveloped governance practices.
One of the companies highlighted in the New Sustainability Champions report was Filipino firm Manila Water.
The report said the utility company was using community partnerships, watershed management, and flexible payment options to boost access to clean water.
Another business to make the 16 best performers was Kenya's Equity Bank, which the study said had pioneered mobile banking in its nation's rural areas.
"While demonstrating superior industry performance and operational efficiency, the New Sustainability Champions innovate to overcome the real constraints that they face," said Knut Haanaes, a BCG partner.
"They proactively engage with all stakeholder groups and positively influence their environments.
"As a result, they generate steady profitable growth and are role models for their regions and industries."
The report comes as the World Economic Forum continues to meet in Dalian, China.
SOURCE: WORLD ECONOMIC FORUM/BCG
Brazil
Grupo Balbo
Sugar production
Natura
Cosmetics
Chile
Masisa
Forestry/manufacturing
Costa Rica
Florida Ice & Farm
Food and beverages
Egypt
Sekem
Agriculture
Hong Kong
MTR Corporation
Transportation
India
Jain Irrigation Systems
Manufacturing/agriculture
Shree Cement
Cement
Suzlon
Renewable energy
Kenya
Equity Bank
Financial services
Papua New Guinea
New Britain Palm Oil
China
Broad Group
Manufacturing
Suntech
Zhangzidao Fishery
Aquaculture
Philippines
Manila Water
Infrastructure
South Africa
Woolworths
Retail